Science of Candy: Caramelization & Caramels | Exploratorium (2024)

Caramelization and caramels are not the same.

Yes, it’s a little bit confusing, but you’ll get it in a minute.

Science of Candy: Caramelization & Caramels | Exploratorium (1) Caramels are the chewy candies you are familiar with. They’re made by cooking sugar, cream, corn syrup, and butter to 245° F. Their brown color comes from a reaction between the sugar and the protein in the cream. This reaction is called the Maillard reaction, after the French scientist who discovered it. The rich brown color of toasted nuts and barbecued meats also comes from the Maillard reaction.

Put simply, the Maillard reaction occurs when part of the sugar molecule (the aldehyde group, if you must know) reacts with the nitrogen part of the protein molecule (an amino group). The resulting series of reactions is not well understood even by food scientists, but it leads to the brown color and many flavorful compounds that are yet to be identified.

Science of Candy: Caramelization & Caramels | Exploratorium (2) Caramelization is what happens to pure sugar when it reaches 338° F. A few tablespoons of sugar put in a pan and heated will eventually melt and, at 338° F, start to turn brown. At this temperature, the sugar compounds begin to break down and new compounds form.

As with the Maillard reaction, the details of what happens during caramelization aren’t well understood. But the results are appreciated all the same. For example, caramelized sugar is often used as decoration on fancy desserts. Try caramelizing sugar yourself —it’s easy!

You can also try making flan !

Science of Candy: Caramelization & Caramels | Exploratorium (2024)

FAQs

What is the science behind caramel candy? ›

The caramel color of caramels comes from a reaction between the sugar and the protein in cream. Called the Maillard reaction, it's the same chemical process that happens when you toast nuts, barbecue meats , or put on self-tanning lotion.

What happens scientifically in caramelisation? ›

Whatever your choice, once a temperature of 160°C has been reached, the heat will cause the sucrose molecules to break up into fructose and glucose molecules. These will then be transformed (“by decomposition”) into aromatic molecules.

What is the science behind candy making? ›

Heating up the solution forces the sucrose molecules to break up and caramelize. But when we do that, the sugar molecules really want to crystallize back into their solid form. Candy-makers use that crystallization process, and some strategic interference, to create the candies that we know and love.

What is the science of caramelizing sugar? ›

Caramelization is what happens when any sugar is heated to the point that the molecules undergo chemical reactions with oxygen in the air and with each other – the molecules either break apart into smaller molecules, or combine with one another to make larger molecules.

What is the difference between caramel and caramelized sugar? ›

While caramelization can be achieved by simply heating sugar, other ingredients including butter, milk, and vanilla are often added afterward to produce a thick, creamier caramel used in sauces, drizzles, candies, and classic caramel apples.

Is there a difference between caramel and caramels? ›

Generally, “caramel” is defined as a chewy, light-brown candy made from butter, sugar, and milk or cream. For example: I love eating caramels because they are soft and chewy. In contrast, “Carmel,” is used as a proper noun, and it is a popular beach town in California, known as Carmel-by-the-Sea.

Why add water to sugar when making caramel? ›

Keep a close eye on the color of the sugar and as it approaches a reddish-brown, remove it from the heat. When making a wet caramel, water is added to help dissolve the sugar before cooking.

Why add butter to caramel? ›

Once the sugar has all dissolved and turned brown, we add butter. The heat of the caramel will melt the butter and create even more wonderful flavors.

What is the principle of caramelization? ›

Like the Maillard reaction, caramelization is a type of non-enzymatic browning. Unlike the Maillard reaction, caramelization is pyrolytic, as opposed to being a reaction with amino acids. When caramelization involves the disaccharide sucrose, it is broken down into the monosaccharides fructose and glucose.

What is the biggest factor in candy making? ›

At the heart of candy-making is sugar. The type, quantity, and crystalline structure of sugar used significantly impact a candy's taste and texture. Candy-making is a temperature-sensitive process. The way sugar is heated and cooled can result in a variety of sweets, from hard candies to gooey caramels.

What are the 6 stages of candy making? ›

The Cold Water Candy Test
  • Thread Stage. 230° F–235° F. sugar concentration: 80% ...
  • Soft-Ball Stage. 235° F–240° F. sugar concentration: 85% ...
  • Firm-Ball Stage. 245° F–250° F. sugar concentration: 87% ...
  • Hard-Ball Stage. 250° F–265° F. sugar concentration: 92% ...
  • Soft-Crack Stage. 270° F–290° F. ...
  • Hard-Crack Stage. 300° F–310° F.

What is the principle of candy making? ›

The technology of candy making is based on the science and art of altering sugar, the principal ingredient in candy, particularly to achieve special textural effects. Thisis accomplished primarily by controlling the state of crystallization of the sugar and the sugar– moisture ratio.

What is the Maillard reaction in caramels? ›

Caramels are the chewy candies you are familiar with. They're made by cooking sugar, cream, corn syrup, and butter to 245° F. Their brown color comes from a reaction between the sugar and the protein in the cream. This reaction is called the Maillard reaction, after the French scientist who discovered it.

What breaks down caramelized sugar? ›

When making caramel at your stovetop, you might assume that the granulated sugar crystals are melting into a sauce — they're not. Instead, the sugar is undergoing a complex chemical reaction in which the chemical compounds break down by heat, without the use of a protein or enzyme to speed up the process.

What is the chemical reaction in caramel? ›

As you heat the ingredients in the pan, you create what is called a Maillard reaction. This chemical reaction occurs when amino acids in your proteins (butter and condensed milk) is combined with sugar and heat, resulting in a series of reactions that cause the brown color you see and the rich flavors you taste.

What is the scientific definition of caramel? ›

caramel, candy substance obtained by boiling sugar to or beyond approximately 240 °F (115 °C), at which point its mass takes on a slightly yellowish colour and pleasantly burnt smell.

What is the science behind salted caramel? ›

Overall, the science behind the flavour of salted caramel is a complex interplay of taste buds, neurotransmitters, and aroma receptors. The combination of sweet and salty flavours creates a satisfying and delicious taste experience that has captured the hearts and taste buds of people around the world.

Why does sugar clump when making caramel? ›

The sugar crystals have jagged edges and, even after liquefying, want to regroup into a solid mass. Stirring a wet caramel encourages these crystals to hook up—and cause clumping.

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